Control
of Odors from Construction and Demolition Debris Landfills
Dr.
Timothy Townsend, University of Florida
Construction
and demolition (C&D) debris landfills sometimes experience
odor problems as a result of reduced sulfur compounds produced
in the landfill. The most notable reduced sulfur compound is hydrogen
sulfide (H2S). The production of H2S and other reduced sulfur compounds
has been linked to the disposal of gypsum wall-board. Previous
research efforts have explored the occurrence of H2S at C&D
debris landfills and in simulated laboratory experiments. Recent
laboratory work has also examined the use of different types of
cover soil to "filter" H2S from the gas before it leaves
the landfill. This project expands this research to the field.
The emissions of H2S from actual C&D debris landfills will
be measured using a flux chamber. At one field site, different
cover soil types will be used to assess the ability of various
materials to attenuate H2S emissions.
Research
Advancing the Management of Construction and Demolition Debris
in Florida
Dr.
Timothy Townsend, University of Florida
This
project targets three tasks whose objectives are to advance the
practice of C&D debris management in Florida.
Task 1: H2S Odors at C&D Debris Landfills - To examine the long
term performance of soil amendments for mitigating hydrogen sulfide
emissions from C&D debris landfills (in the field) and to evaluate
factors impacting H2S control (in the field and in the lab).
Task 2: Engineered Wood - To examine potential environmental concerns
associated with the inclusion of engineered wood products such as
plywood and oriented strand board (OSB) in landscape mulch.
Task 3: Portland Cement Concrete - To compile all available federal
and state specifications (and possibly international) regarding the
reuse of crushed portland cement concrete for road base construction
stone and to foster a dialogue between all appropriate parties to
determine what actions are needed to overcome existing impediments.
Soils
underneath Florida Landfills and their Role in the Occurrence
and Fate of Iron and Arsenic in Groundwater
Dean
R. Rhue , Ph.D. – UF
Several landfill sites in Florida are experiencing elevated iron
concentrations in the groundwater wells. The iron rich soil is being
hypothesized as source of iron. Similarly the disposal of arsenic
treated wood in unlined C&D landfills is a concern for potential
groundwater contamination due to arsenic (As) leaching from the wood.
The two issues are interrelated since changes to the redox conditions
can have a strong impact on the fate of both As and Fe. The fate
of As is very much tied to chemistry of iron; iron soils have a strong
ability to adsorb arsenic from water. The fact that reducing condition
under landfills may cause iron to be released suggests that As will
also be released and might be more mobile than expected based on
soil properties alone.
The primary objectives of this project are to quantify the contribution
that soils beneath landfills can make to iron in groundwater and
to evaluate the ability of soils beneath C&D debris landfills
to retain and hold arsenic against leaching. Elevated iron concentrations
have been noted at a growing number of facilities in the state, both
lined and unlined, but the source of the iron is unknown. This study
will attempt to relate the chemical, physical, and hydrologic properties
of these soils to their iron releasing potential. The second issue
is the fate of As from CCA-treated wood at C&D debris landfills.
The ability of soils to retain arsenic depends on the chemical and
physical properties of the soil as well as the chemical properties
of the surrounding solution, such as redox potential and presence
of organic and inorganic ligands. These factors will be quantified
to the extent possible and utilized in an existing transport model
to evaluate the leaching potential of arsenic beneath C&D Landfills.